Application
Zeron® 100 stands out for its extraordinary ability to resist corrosion and erosion in a wide range of aggressive environments. The special Cu+W combination significantly improves resistance to sulfuric and hydrochloric acids, compared to similar alloys without such additives. Thanks to its high resistance to pitting and stress corrosion cracking, Zeron® 100 is widely used in offshore applications, especially in seawater contexts. This material also offers excellent resistance to caustic alkalis and phosphoric acid. Its service temperature range generally varies between -50 °C and 280 °C, with the upper limit due to thermal instability (450 °C and sigma phase embrittlement). Zeron® 100 is highly valued in the oil and gas production sector and is used in a wide range of applications, including process piping, risers, manifolds, pressure vessels, valves, pumps, desalination plants, flue gas desulfurization (FGD) systems, and in the mining, chemical, and pharmaceutical industries. Furthermore, Zeron® 100 wires are ideal for joining supermartensitic stainless steels.
Alloy Type
25%Cr ferritic-austenitic superduplex stainless steels matching the proprietary Zeron® 100 alloy.
Microstructure
Austenite-ferrite duplex microstructure in AW or solution annealed condition with an approximate 30- 60% ferrite level, depending on heat cycle conditions.
Materials
  • EN W.Nr.: 1.4508, 1.4501, 1.4469
  • ASTM: A890 6A, A182 F55, A890 5A
  • UNS: S32760, J93380, S32750, S32550, S32520, S39274, S32950, J93404
  • PROPRIETARY: Zeron 100 (Rolled Alloys) DP3W (Nippon Steel Corporation), 7-Mo Plus (Carpenter), SAF 2507 (Sandvik)
Welding & PWHT
For welding Zeron® 100, preheating is generally not required. The interpass temperature should not exceed 150 °C. A heat input between 1.0 and 2.0 kJ/mm (based on the material thickness) is considered optimal, though many industrial codes set a maximum limit of 1.5 or 1.75 kJ/mm. While welds in wrought duplex stainless steels are usually left as is, major repairs on castings often require a solution treatment. Field tests confirm that good properties are obtained by following a water quench treatment at 1120 °C for a period between 3 and 6 hours.

Products of the line ZERON 100

Product name Process AWS specifications EN ISO specifications
DAIKOWT 2594Cu GTAW
AWS A5.9
ER2594
EN ISO 14343-A
W 25 9 4 N L
DAIKOWM 2594Cu GMAW
AWS A5.9
ER2594
EN ISO 14343-A
G 25 9 4 N L
DAIKOWS 2594Cu SAW
AWS A5.9
ER2594
EN ISO 14343-A
S 25 9 4 N L
G-TECH 2595B SMAW
AWS A5.4
E2595-15
EN ISO 3581-A
E 25 9 4 N L B 42
DAIKOFCW 2595 FCAW
AWS A5.22
E2594T0-4
EN ISO 17633-A
T 25 9 4 Cu N L R M21 3

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