DAIKOWS 9CrMoV

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  • CREEP RESISTING STEELS
9CrMoV

Description

9%Cr-1%Mo V solid wire for elevate temperature service
Submerged arc wire designed for P91 type alloyed steels and steels for pressurized hydrogen service, particularly in oil refineries prolonged elevated temperature service up to about 650°C, especially in oil refineries (piping, heat exchangers, pressure vessels, boiler superheater). The additions of Nb, V and N improve creep resistance properties compared to 9%Cr 1%Mo.
Specifications
ISO 24598-A
S CrMo91 FB
AWS A5.23
EB9
Shielding
DAIKOFLUX 982
Positions
PA, PB, PC
Current
DC/AC
Packaging Type
K415 spool and drums.
Asme qualifications
F-No (QW432)
6
A-No (QW442)
5
Chem. Comp. %
DEFAULT
C
0.1
Mn
0.6
Ni
0.6
Cr
8.8
N
0.4
Nb
0.06
V
0.2
P
0.005
S
0.003
Mo
0.95
Si
0.2
Cu
0.04
Mechanical Properties
min
variant
Tensile strength Rm MPa
620
750
Yield strength Rp0.2 MPa
435
670
Elongation A (L0=5d0) %
18
20
Impact Charpy ISO-V
34J @ 20°C
40J @ -20°C
Impact Charpy ISO-V
-
-
Welding Parameters
2.4 mm
3.2 mm
4 mm
Ampere
350A - 450A
430A - 530A
480A - 580A
Voltage
27V - 31V
27V - 31V
27V - 31V
Packaging
Ø 2,0÷4,0mm
Ø 2,0÷4,0mm
Ø 2,0÷4,0mm
Packaging Type
K415 spool and drums.
K415 spool and drums.
K415 spool and drums.
Description

Application

These consumables have been specifically engineered for the welding of 'type 91' 9CrMo steels, which have been modified through the addition of small amounts of niobium, vanadium, and nitrogen to enhance their long-term creep properties. The primary purpose of these consumables is to cater to the requirements of high-integrity structural applications operating at elevated temperatures. The alloy enhancements responsible for augmenting creep strength have been meticulously calibrated to exceed the minimum thresholds necessary for ensuring optimal performance. In this particular scenario, weldments are susceptible to being weakest in the softened (intercritical) Heat-Affected Zone (HAZ) of the parent material. This vulnerability is evident in the occurrence of 'type IV' failures during transverse weld creep tests. Modified 9CrMo steels have gained widespread application in critical components such as headers, main steam piping, valves, and turbine casings within fossil-fueled power generation plants. Furthermore, there is potential for their future deployment in sectors such as oil refineries, as well as coal liquefaction and gasification plants.

Alloy Type

Modified 9CrMo for high temperature creep resistance.

Microstructure

In the PWHT condition the microstructure consists of tempered martensite with alloy carbides.

Materials


EN W.Nr.: 1.4903 (X10CrMoVNb 9 1).
ASTM: A 213 T91 (seamless tubes), A 335 P91 (seamless pipes), A 387 Gr 91 (plates), A 182 / A336 F91 (forgings), A 217 C12A (castings), A 234 WP91, A 369 FP91.
ANFOR: NF A-49213/A-49219 Gr TU Z 10 CDVNb 09-01.

Welding & PWHT

The prescribed minimum preheat temperature is 150°C, coupled with a maximum interpass temperature of 300°C. In practical terms, a preheat-interpass range within 200–300°C is considered standard. To ensure the complete transformation to martensite, it is imperative to cool welds to approximately 100°C before undergoing post-weld heat treatment (PWHT). ASME base material codes and AWS consumable classifications permit PWHT down to 730°C, whereas EN consumable classifications specify 750°C. Optimal material properties are achieved by maintaining a tempering parameter (P) of around 21 or higher, where P = °C + 273 (log t + 20) x 10–3. The maximum PWHT temperature varies; AWS consumable specifications allow 760°C, while EN permits 770°C. EN 10222-1 allows for a maximum of 790°C for base material forgings. In comparison to directly matching weld metal, incorporating some nickel and reducing niobium proves beneficial in enhancing toughness after a conveniently brief PWHT at 750–760°C. It is generally discouraged to conduct PWHT above 765°C for Ni-containing consumables due to the potential re-hardening resulting from the proximity to Ac1. Some regulatory bodies recommend maintaining weld metal Ni + Mn below 1.5% to sustain a sufficiently high Ac1 for potential higher PWHT temperatures, if necessary.

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